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KMID : 1059520120560030348
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Journal of the Korean Chemical Society
2012 Volume.56 No. 3 p.348 ~ p.356
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Synthesis, Structure Investigation and Dyeing Assessment of Novel Bisazo Disperse Dyes Derived from 3-(2'-Hydroxyphenyl)-1-phenyl-2-pyrazolin-5-ones
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Metwally M. A.
Bondock S. A.
El-Desouky S. I.
Abdou M. M.
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Abstract
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In an attempt to find a new class of bisazo disperse dyes with better dyeing properties, a series of novel bisazo dyestuffs based on 4-arylhydrazono-3-(2'-hydroxyphenyl)-1-phenyl-2-pyrazolin-5-ones 3a-f were prepared by diazocoupling of p-nitrophenyl diazonium chloride with 4-arylhydrazono-3-(2'-hydroxyphenyl)-1-phenyl-2-pyrazolin-5-ones 2a-f. Compounds 3a-f were subsequently reacted with acetic anhydride in the presence of p-toluenesulfonic acid afford the corresponding O-acetyl derivatives 4a-f. The latter products as well as spectral data indicated that compounds 3a-f exist predominantly in the azo-hydrazone tautomeric form (H) as the ZE-configuration. Additionally, two series of the synthesized dyes 3a-f and 4a-f were applied as disperse dyes for dyeing polyester fabrics and their fastness properties were evaluated. Also the position of color in CIELAB coordinates (L*, a*, b*, H*, C*) was assessed.
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KEYWORD
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Bisazo pyrazolin-5-ones, Azo-hydrazone tautomerism, Fastness properties, CIELAB coordinates
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